!wB97X 6-31g(d) AllPop opt numfreq CPCM

%cpcm 
	smd true
	SMDsolvent "water"
end

*xyz 0 1
 C                  1.58831700   -0.52285100    0.00000900
 H                  2.24356700   -0.50462000   -0.88145200
 H                  1.05403800   -1.47795800   -0.00011600
 H                  2.24338700   -0.50474800    0.88160700
 C                  0.66782200    0.66509400    0.00000200
 H                  1.17002200    1.63386300    0.00001100
 C                 -0.66782200    0.66509500   -0.00000500
 H                 -1.17002200    1.63386300   -0.00000800
 C                 -1.58831600   -0.52285100   -0.00000900
 H                 -2.24348500   -0.50468000    0.88151500
 H                 -2.24347000   -0.50468900   -0.88154400
 H                 -1.05403700   -1.47795800    0.00000300
*